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Non-volatile memory elements based on the intercalation of organic molecules inside carbon nanotubes...

by Vincent Meunier, Sergei V Kalinin, Bobby G Sumpter
Publication Type
Journal
Journal Name
Physical Review Letters
Publication Date
Page Number
056401
Volume
98

We propose a novel class of non-volatile memory elements based on the modification of the transport properties of a conducting carbon nanotube by the presence of a guest molecule having multiple stable orientational states relative to the nanotube that correspond to conducting and non-conducting states. The mechanism, governed by a local gating effect of the molecule on the electronic properties of the nanotube host, is studied using density functional theory. The mechanisms of reversible reading and writing of information are illustrated with a F4 TCNQ molecule encap-sulated inside a metallic carbon nanotube. Our results suggest that this new type of non-volatile
memory element is robust, fatigue-free, and can operate at room temperature.