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Proton conduction in electrolyte made of manganese dioxide for hydrogen gas sensor...

by Hideki Koyanaka, Yoshikatsu Ueda, K Takeuchi, Alexander I Kolesnikov
Publication Type
Conference Paper
Publication Date
Page Numbers
497 to 499
Volume
N/A
Conference Name
The 14th International Meeting on Chemical Sensors
Conference Location
Nürnberg, Germany
Conference Date
-

We propose a network model of oxygen-pairs to store and conduct protons on the surface of manganese dioxide with a weak covalent bond like protons stored in pressured ice. The atomic distances of oxygen-pairs were estimated between 2.57 and 2.60 angstroms in crystal structures of ramsdellite-type and lambda-type manganese dioxides by using protonated samples and inelastic neutron scattering measurements. Good properties for a hydrogen gas sensor using electrolytes made of manganese dioxides that contain such oxygen-pairs were confirmed experimentally.