The interface between metallic oxide lanthanum strontium manganite (LSMO) and ferroelectric bismuth ferrite (BFO) was studied by STEM for both polarization orientations. The images showed local lattice expansion for negative-interface polarization charge, but not for positive. In the region where local lattice expansion was observed, EELS spectra indicate oxygen depletion as well as oxidation state changes for constituent metals, suggesting that the negative polarization charge was compensated by positively charged oxygen vacancies. For the interface with positive polarization charge, none of these phenomena were seen, suggesting purely electronic compensation. First principles calculations were consistent with oxygen vacancies causing local lattice expansion in BFO, while mesoscopic Ginzburg-Landau modeling helped explain additional observed phenomena, such as formation of exclusion layers.
Young-Min Kim, Anna Morozovska, Eugene Eliseev, Mark P. Oxley, Rohan Mishra, Sverre M. Selbach, Tor Grande, S. T. Pantelides, Sergei V. Kalinin and Albina Y. Borisevich, “Direct observation of ferroelectric field effect and vacancy-controlled screening at the BiFeO3/LaxSr1-xMnO3 interface,” Nature Materials (2014). http://dx.doi.org/10.1038/nmat4058
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