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Absence of long-range chemical ordering in equimolar FeCoCrNi...

Publication Type
Journal
Journal Name
Applied Physics Letters
Publication Date
Page Number
251907
Volume
100
Issue
25

Equimolar FeCoCrNi alloys have been the topic of recent research as “high-entropy
alloys,” where the name is derived from the high configurational entropy of mixing for
a random solid solution. Despite their name, no systematic study of ordering in this
alloy system has been performed to date. Here we present results from anomalous
x-ray scattering and neutron scattering on quenched and annealed samples. An alloy
of FeNi3 was prepared in the same manner to act as a control. Evidence of longrange
chemical ordering is clearly observed in the annealed FeNi3 sample from both
experimental techniques. The FeCoCrNi sample given the same heat treatment lacks
long-range chemical order.