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Charge Order, Dynamics, and Magnetostructural Transition in Multiferroic LuFe2O4...

Publication Type
Journal
Journal Name
Physical Review Letters
Publication Date
Page Number
227602
Volume
101
Issue
22

The cascade of temperature and field-driven transitions in LuFe<2/>O<4/> was investigated byM�Nossbauer and optical spectroscopies, magnetization, and x-ray scattering. A correlation of Fe2+ ��Fe3+ charge transfer excitations with the 320 K phase transition below which uperstructure reflections appear confirms its association with gradual charge carrier freezing. Fe2+ on-site excitations are sensitive to the 175 K magnetic transition, which Bragg splitting and large magneto optical contrast suggest involes a monoclinic distortion that can be driven by both temperature and magnetic field.
PACS numbers: 71.30.+h,75.30.Kz,78.20.Ci,76.70.+y