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Chemically controlled crystal growth of (CH3NH3)2AgInBr6...

Publication Type
Journal
Journal Name
CrystEngComm
Publication Date
Page Numbers
5929 to 5934
Volume
20
Issue
39

We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH3NH3)2AgInBr6. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb2+ (from CH3NH3PbBr3) to modulate the soluble intermediates and force formation of (CH3NH3)2AgInBr6. Our results provide insights into mechanism and design-driven crystal growth and discovery of new halide materials that are chemically related to perovskites with photovoltaic and related applications.