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Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability...

Publication Type
Journal
Journal Name
Inorganic Chemistry Frontiers
Publication Date
Page Numbers
2018 to 2022
Volume
5
Issue
8

A simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al3+ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m2 g−1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.