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A coordinatively saturated sulfate encapsulated in a metal-organic framework functionalized with urea hydrogen-bonding groups...

by Radu Custelcean, Bruce A Moyer, Benjamin P Hay
Publication Type
Journal
Journal Name
Chemical Communications
Publication Date
Page Numbers
5971 to 5973
Volume
N/A
Issue
48

A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag2SO4 resulted in the formation of a 1D metal - organic framework that encapsulates SO42- anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.