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Direct measurement of the chemical reactivity of silicon electrodes with LiPF6-based battery electrolytes...

Publication Type
Journal
Journal Name
Chemical Communications
Publication Date
Page Numbers
3081 to 3084
Volume
50
Issue
23

We report the first direct measurement of the chemistry and extent of reactivity between a lithium ion battery electrode surface (Si) and a liquid electrolyte (1.2M LiPF6-3:7 wt% ethylene carbonate:dimethyl carbonate). This layer is estimated to be 3.6 nm thick and partially originates from the consumption of the silicon surface.