Skip to main content
SHARE
Publication

Dynamics at the Polymer/Nanoparticle Interface in Poly(2-vinylpyridine)/Silica Nanocomposites....

Publication Type
Journal
Journal Name
Macromolecules
Publication Date
Page Numbers
1837 to 1843
Volume
47
Issue
5

The static and dynamic properties of poly(2-vinylpyridine)/silica nanocomposites are investigated by
temperature modulated differential scanning calorimetry, broadband dielectric spectroscopy (BDS), small-angle X-ray scattering (SAXS), and transmission electron microscopy. Both BDS and SAXS detect the existence of an interfacial polymer layer on the surface of nanoparticles. The results show that whereas the calorimetric glass transition temperature varies only weakly with nanoparticle loading, the segmental
mobility of the polymer interfacial layer is slower than the bulk polymer by 2 orders of magnitude. Detailed analysis of BDS and SAXS data reveal that the interfacial layer has a thickness of 4−6
nm irrespective of the nanoparticle concentration. These results demonstrate that in contrast to some recent articles on polymer nanocomposites, the interfacial polymer layer is by no means a “dead layer”. However, its existence might provide some explanation for controversies surrounding the dynamics of polymer nanocomposites.