Publication Type
Journal
Journal Name
Chemical Communications
Publication Date
Page Number
11807
Volume
52
Abstract
Hydrogen release from Al-based complex hydrides composed of
metal cation(s) and [AlH4] was investigated using inelastic neutron
scattering viewed from vibrational dynamics. The hydrogen release
followed the softening of translational and [AlH4] librational
modes, which was enhanced by vibrational dynamics and the
valence(s) of the metal cation(s).
