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Identifying the Role of N-Heteroatom Location in the Activity of Metal Catalysts for Alcohol Oxidation...

by Carine Chan-thaw, Gabriel M Veith, Alberto Villa, Laura Prati
Publication Type
Journal
Journal Name
ChemCatChem
Publication Date
Page Numbers
1338 to 1346
Volume
7
Issue
8

This work focuses on understanding how the bonding of nitrogen heteroatoms contained on/in a activated carbon support influence the stability and reactivity of a supported Pd catalyst for the oxidation of alcohols in solution. The results show that simply adding N groups via solution chemistry is insufficient to improve catalytic properties. Instead a strongly bound N moiety is required to activate the catalyst and stabilize the metal particles.