Abstract
Choline-based amino acid ionic liquids with anions glycinate, β-alaninate, phenylalaninate, and prolinate were synthesized and mixed with ethylene glycol to form lower-viscosity benign eutectic solvents for CO2 capture. The highest capacity measured was 0.7 moles of CO2 per mole of ionic liquid (2 moles CO2 per kg solvent) for a 1 to 2 mole ratio mixture of choline prolinate to ethylene glycol at 1 bar of CO2 and 25 °C. Under 5000 ppm of CO2, half of this capacity was realized. Through a combined study of quantitative 13C NMR spectroscopy, molecular dynamics simulations and density functional theory calculations, we show that hydrogen bonding in the eutectic solvent prevents proton-transfer between prolinate anions upon CO2 absorption, which occurs in the absence of ethylene glycol and deactivates binding sites. Blocking this proton transfer leads to a higher binding capacity compared to neat choline prolinate. This work demonstrates the impact of hydrogen bonding on the CO2 binding mechanism and energetics, as well as physical and thermal properties in eutectic solvents, thus addressing an unmet need and informing future studies on the development of benign sorbents for capturing CO2 from dilute streams.
