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Influence of lithium salts on the discharge chemistry of Li-air cells...

by Gabriel M Veith, Jagjit Nanda, Laetitia H Delmau, Nancy J Dudney
Publication Type
Journal
Journal Name
Journal of Physical Chemistry Letters
Publication Date
Page Numbers
1242 to 1247
Volume
3
Issue
10

In this work we show that the use of a high boiling point ether solvent (tetraglyme) promotes the formation of Li2O2 in a lithium-air cell. In addition, another major constituent in the discharge product of a Li-air cell contains halides, from the lithium salt, and the tetraglyme used as the solvent. This information is critical to the development of Li-air electrolytes which are stable and promote the formation of the desired Li2O2 products.