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Itinerant antiferromagnetism in BaCr2As2: Experimental characterization and electronic structure calculations...

Publication Type
Journal
Journal Name
Physical Review B
Publication Date
Volume
79
Issue
9

We report single crystal synthesis, specific heat and resistivity measurements and electronic structure calculations for BaCr2As2. This material is a metal with itinerant antiferromagnetism, similar to the parent phases of Fe-based high temperature superconductors, but differs in magnetic order. Comparison of bare band structure density of states and the low temperature specific heat implies a mass renormalization of 2. BaCr2As2 shows stronger transition metal - pnictogen covalency than the Fe compounds, and in this respect is more similar to BaMn2As2. This provides an explanation for the observation that Ni and Co doping is effective in the Fe-based superconductors, but Cr or
Mn doping is not.