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Lattice distortions and oxygen vacancies produced in Au+ irradiated nano-crystalline cubic zirconia...

by Philip D Edmondson, William J Weber, Fereydoon Namavar, Yanwen Zhang
Publication Type
Journal
Journal Name
Scripta Materialia
Publication Date
Page Numbers
675 to 678
Volume
65
Issue
8

The structural impact of oxygen vacancies in nanocrystalline cubic zirconia is investigated. A non-equilibrium number of oxygen vacancies in introduced to the lattice by ion irradiation. The lattice is observed to be initially compressed, undergoes a relaxation at 0.7 displacements per atom (dpa), and experiences a contraction before reaching a temperature dependent steady state value at above 7 dpa. The level of lattice distortion is related to the charge state of the accumulating oxygen vacancies.