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Local correlated motions in aqueous solution of sodium chloride...

Publication Type
Journal
Journal Name
Physical Review Materials
Publication Date
Page Number
065604
Volume
3
Issue
6

Real-space motions of molecules and ions in an aqueous solution of sodium chloride are studied with high-resolution inelastic x-ray scattering. We focus on the correlated dynamics of water molecules and salt ions, instead of the instantaneous structure and the rotational and reorientation dynamics that have been studied using scattering techniques and optical spectroscopy, respectively. The real-space analysis in terms of the Van Hove function illustrates the effect of salt ions to slow down the local correlated dynamics of surrounding water in the hydration shells.