Abstract
We investigate the chemical substitution of group 5 into BaFe2As2 (“122”) iron arsenide, in the effort to understand why Fe-site hole doping of this compound (e.g., using group 5 or 6) does not yield bulk superconductivity. We find an increase in the c-lattice parameter of the BaFe2As2 with the substitution of V, Nb, or Ta; the reduction in c predicts the lack of bulk superconductivity [Konzen and Sefat, J. Phys.: Condens. Matter 29, 083001 (2017)] that is confirmed here through transport and magnetization results. However, our spectroscopy measurements find a coexistence of antiferromagnetic and local superconducting nanoscale regions in V-122, observed in a transition-metal hole-doped iron arsenide. In BaFe2As2, there is a complex connection between local parameters such as composition and lattice strain, average lattice details, and the emergence of bulk quantum states such as superconductivity and magnetism.
