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Magnetic Neutron Scattering of Thermally Quenched K-Co-Fe Prussian Blue...

Publication Type
Journal
Journal Name
Physical Review B
Publication Date
Page Number
054431
Volume
86
Issue
5

Magnetic order in the thermally quenched photomagnetic Prussian blue analogue coordination
polymer K0.27Co[Fe(CN)6]0.73[D2O6]0.27-1.42D2O has been studied down to 4 K with unpolarized
and polarized neutron powder di raction as a function of applied magnetic eld. Analysis of the
data allows the onsite coherent magnetization of the Co and Fe spins to be established. Speci cally,
magnetic elds of 1 T and 4 T induce moments parallel to the applied eld, and the sample behaves
as a ferromagnet with a wandering axis.