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Metamagnetic Phase Transition in a Diruthenium Compound with Interpenetrating Sublattices...

by Randy S Fishman, Joel Miller
Publication Type
Journal
Journal Name
Polyhedron
Publication Date
Page Numbers
3131 to 3133
Volume
30
Issue
18

The diruthenium compound [Ru2(O2CMe)4]3[Cr(CN)6] may be the only known material that con- tains two weakly-coupled, magnetically-ordered sublattices occupying the same three-dimensional volume. Due to the strong easy-plane anisotropy on each Ru2 complex, the moment of each sub- lattice is constrained to one of the eight cubic diagonals. At low fields, the two sublattices are antiferromagnetically aligned by weak dipolar and deformation energies. But above a metamagnetic critical field of about 1000 Oe, the sublattice moments become ferromagnetically aligned and the net magnetization increases dramatically. We have successfully modeled this metamagnetic tran- sition by assuming that the individual sublattice spin configurations are only weakly distorted by the magnetic field. This model suggests that the ground state of each sublattice undergoes a phase transition at a pressure of about 7 kbar. The drop in the sublattice moment and the rise in the sublattice susceptibility above 7 kbar can be explained by a high- to low-spin transition (S = 3/2 to 1/2) on the mixed-valent diruthenium complexes.