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Near-Field Enhanced UV Resonance Raman Spectroscopy Using Aluminum Bow-tie Nano-antenna...

by Ling Li, Shuang Fang Lim, Alexander A Puretzky, Robert Riehn, Hans Hallen
Publication Type
Journal
Journal Name
Applied Physics Letters
Publication Date
Page Number
113116
Volume
101
Issue
11

An aluminum bow-tie nano-antenna is combined with the resonance Raman e ect in the deep ultraviolet to
dramatically increase the sensitivity of Raman spectra to a small volume of material, such as benzene used
here. We further demonstrate gradient- eld Raman peaks for several strong IR modes. We achieve a gain
of  105 in signal intensity from the near eld enhancement due to the surface plasmon resonance in the
aluminum nanostructure. The on-line resonance enhancement contributes another factor of several thousands,
limited by the laser line width. Thus, an overall gain of hundreds of million is achieved.