Abstract
The cost-effectiveness and excellent performance of conductive-carbon-supported Ni-based electrocatalysts make them attractive materials for hydrogen oxidation and evolution reactions. However, they were previously unused in gas-phase hydrogenation reactions. In this work, we have expanded the applicability of commercially available advanced Ni/C, NiMo/C and NiRe/C materials from electrocatalysis to heterogeneous catalysis of CO2 methanation. Our catalytic testing efforts indicate that the monometallic Ni/C material demonstrates the best CO2 methanation properties, achieving an excellent CO2 conversion of 83 % at 400 °C with nearly complete selectivity to CH4 of 99.7 %, plus exhibiting intact performance during 90 h of time-on-stream testing. Such catalytic properties are among the highest reported to date among carbon-supported Ni-based methanation catalysts. Excellent performance of Ni/C stems from the good dispersion of the Ni nanoparticles over N-containing carbon support material.
