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Pd-Metalated Conjugated Nanoporous Polycarbazoles for Additive-Free Cyanation of Aryl Halides: Boosting Catalytic Efficiency ...

Publication Type
Journal
Journal Name
ChemSuSChem
Publication Date
Page Numbers
2348 to 2351
Volume
10
Issue
11

A novel spatial-modulation approach was developed to fabricate a new heterogeneous Pd-metalated nanoporous polymer for efficient and ligand-free cyanation of aryl halides. The resulting catalyst displays high activity in the synthesis of benzonitriles, including high product yield, excellent stability and recycle, and broad scope functional group tolerance.