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Seven-coordinate anion complex with a tren-based urea: Binding discrepancy of hydrogen sulfate in solid and solution states...

Publication Type
Journal
Journal Name
Organic and Biomolecular Chemistry
Publication Date
Page Numbers
4444 to 4447
Volume
9
Issue
12

Structural characterization of a hydrogen sulfate complex
with a tren-based urea suggests that the anion is coordinated
with sixNH◊ ◊ ◊Obonds (dN ◊ ◊ ◊ O = 2.857 (3) to 3.092 (3)A° ) and
one OH◊ ◊ ◊O bond (dO ◊ ◊ ◊ O = 2.57 (2) A° ) from three receptors;
however, in solution the anion is bound within the pseudocavity
of one receptor.