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Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles...

Publication Type
Journal
Journal Name
ACS Macro Letters
Publication Date
Page Numbers
1056 to 1059
Volume
6
Issue
10

A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated polycarbazoles with high porosities and promising CO2 storage abilities. This innovative approach constitutes a new direction for the development of novel nanoporous polymer frameworks through sustainable solid-state assembly pathways, and may open up new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.