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Thermoelectric performance of electron and hole doped PtSb2...

by Yasir Saeed, Nirprenda Singh, Udo Schwingenschlogl, David S Parker
Publication Type
Journal
Journal Name
Journal of Applied Physics
Publication Date
Page Number
163706
Volume
113
Issue
16

We investigate the thermoelectric properties of electron and hole doped PtSb2. Our results show that
for doping of 0.04 holes per unit cell (1:5 􏰂 1020 cm􏰃3) PtSb2 shows a high Seebeck coefficient
at room temperature, which can also be achieved at other temperatures by controlling the carrier
concentration (both electron and hole). The electrical conductivity becomes temperature independent when the doping exceeds some 0.2 electrons/holes per unit cell. The figure of merit at 800 K in electron and hole doped PtSb2 is comparatively low at 0.13 and 0.21, respectively, but may increase significantly with As alloying due to the likely opening of a band gap and reduction of the
lattice thermal conductivity