Skip to main content
SHARE
Publication

An unusual slowdown of fast diffusion in a room temperature...

by Chathoth, Eugene Mamontov, Pasquale F Fulvio, Xin Wang
Publication Type
Journal
Journal Name
European Physics Letters
Publication Date
Volume
102
Issue
02955075

Using quasielastic neutron scattering in the temperature range from 290 to 350 K, we
show that the diffusive motions in a room temperature ionic liquid [H2NC(dma)2][BETI] become
faster for a fraction of cations when the liquid is confined in a mesoporous carbon. This applies
to both the localized and long-range translational diffusive motions of the highly mobile cations,
although the former exhibit an unusual trend of slowing-down as the temperature is increased,
until the localized diffusivity is reduced to the bulk ionic liquid value at a temperature of 350 K.