Abstract
This paper presents a comprehensive analysis of the basin-wide inventory of
anthropogenic CO2 in the Atlantic Ocean based on high-quality inorganic carbon,
alkalinity, chlorofluorocarbon, and nutrient data collected during the World Ocean
Circulation Experiment (WOCE) Hydrographic Program, the Joint Global Ocean Flux
Study (JGOFS), and the Ocean-Atmosphere Carbon Exchange Study (OACES) surveys
of the Atlantic Ocean between 1990 and 1998. Anthropogenic CO2 was separated from
the large pool of dissolved inorganic carbon using an extended version of the DC*
method originally developed by Gruber et al. [1996]. The extension of the method
includes the use of an optimum multiparameter analysis to determine the relative
contributions from various source water types to the sample on an isopycnal surface. Total
inventories of anthropogenic CO2 in the Atlantic Ocean are highest in the subtropical
regions at 20–40, whereas anthropogenic CO2 penetrates the deepest in high-latitude
regions (>40N). The deeper penetration at high northern latitudes is largely due to the
formation of deep water that feeds the Deep Western Boundary Current, which transports
anthropogenic CO2 into the interior. In contrast, waters south of 50S in the Southern
Ocean contain little anthropogenic CO2. Analysis of the data collected during the 1990–
1998 period yielded a total anthropogenic CO2 inventory of 28.4 ± 4.7 Pg C in the North
Atlantic (equator-70N) and of 18.5 ± 3.9 Pg C in the South Atlantic (equator-70S).
These estimated basin-wide inventories of anthropogenic CO2 are in good agreement with
previous estimates obtained by Gruber [1998], after accounting for the difference in
observational periods. Our calculation of the anthropogenic CO2 inventory in the Atlantic
Ocean, in conjunction with the inventories calculated previously for the Indian Ocean
[Sabine et al., 1999] and for the Pacific Ocean [Sabine et al., 2002], yields a global
anthropogenic CO2 inventory of 112 ± 17 Pg C that has accumulated in the world oceans
during the industrial era. This global oceanic uptake accounts for approximately 29% of
the total CO2 emissions from the burning of fossil fuels, land-use changes, and cement
production during the past 250 years.