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Technology

Selective Extraction of Lithium from Hot Leachate Sulfate Stream through a Precipitation Process

Topic:

Invention Reference Number

201904541
Lithium mine

Description

The patented method involves mixing an aluminum-containing sorbent, such as aluminum hydroxide or aluminum oxide, with a lithium sulfate aqueous solution to form a precursor mixture. This mixture is then heated to between 50-200°C, leading to the selective formation of a solid lithium-aluminum complex while leaving other salts in solution. The process may further include a step to recover isolated lithium salt by heating the lithium-aluminum complex in water, facilitating the transfer of lithium salt back into solution and producing aluminum hydroxide solid, which can be reused in the process. This innovation provides a less costly and more straightforward solution for lithium recovery from aqueous solutions, notably in the presence of competing ions like sodium and potassium.

Benefits

  • High selectivity for lithium, even in the presence of other alkali metal ions.
  • Cost-effective and efficient process suitable for various lithium-containing aqueous solutions.

Applications and Industries

  • Lithium-ion battery manufacturing and recycling.
  • Production of high-purity lithium for pharmaceuticals, ceramics, and lubricating greases.

Contact

To learn more about this technology, email partnerships@ornl.gov or call 865-574-1051.