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The present invention increases the viability of sodium polysulfide catholytes for nonaqueous redox flow batteries. Low order polysulfides (Na2Sx, x<5) have poor solubility (and thus low capacity) in common aprotic solvents.

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The invention is a material that will selectively absorb lithium from process waters, and then in a subsequent step, allow the lithium to be released and concentrated; allowing efficient lithium extraction from fluids for use as commodity chemicals.