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This invention creates a well bonded, durable optical quality thin film that is superhydrophobic (extremely water repellant), that blocks ultraviolet (UV) radiation and can be deposited in such a way as to be antireflective over a broad spectrum of optical wavelengths.

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The invention provides a facile one-pot method for generating members of a novel family of hydrophobic protic ionic liquids (PILs) derived from pairings between diverse superbases and the superacid-derived anions, [Tf2N–] or [beti–].